Zvaná přednáška – F. Dean Toste

18. června 2012

Prof. F. Dean Toste (University of California, Berkeley, CA, USA)


Concepts and Catalysts for Enantioselective Reactions of C-C Multiple Bonds


This lecture will emphasize a reactivity driven approach to development of electrophilic catalysts for addition, rearrangement and coupling reactions of C-C multiple bonds. More specifically, the application of cationic gold(I) complexes, chiral anions and chiral acids in enantioselective transformations initiated by π-activation will be discussed. Particular attention will be devoted to the mechanistic hypotheses that form the basis for catalyst discovery and the development of new reactions.

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